Preparation, Spectroscopic, Bioactive and Theoretical Studies of Mixed Ligand Complexes

Authors

  • Abbas Ali Salih Al-Hamdani Department of Chemistry, College of Science for Women, University of Baghdad. Iraq
  • Nawres Khalid Gabraael Al-dulyme Department of Chemistry, College of Education for Women, University of Mousl. Iraq
  • Susan Duraid Ahmed Department of Educational and Psychological Science, College of Education Pure Sciences- Ibn Al-Haitham, University of Baghdad, Baghdad, Iraq.
  • Hassan M Basheer 1Department of Chemistry, College of Science for Women, University of Baghdad. Iraq.

Keywords:

Mixed ligand Complexes, 8-hydroxyquinoline, Bioactive, Theoretical Studies

Abstract

The mixed ligands complexes of 8-hydroxyquinoline and Schiff base 1, 5-dimethyl-4-(5-oxohexan-2-ylideneamino)-2-phenyl-1H-pyrazol-3 (2H)-one (L) with Cr(III), Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) ions were prepared. The compounds have been characterized by NMR, FT-IR, UV-Vis and mass spectra, elemental microanalysis (C.H.N.), magnetic moment, chloride contain, atomic absorption and molar conductance. All prepared complexes were octahedral geometry. Compound structures treated theoretically using the program hyper chem. 8 in gas phase at 298°K. The compounds were also screened for their bioactive property such as antifungal and antibacterial.

Published

2017-09-01

Issue

Section

Articles

How to Cite

(1)
Preparation, Spectroscopic, Bioactive and Theoretical Studies of Mixed Ligand Complexes. ANJS 2017, 20 (3), 49-59.