Preparation and Spectroscopic Study of New NS Ligand and its Cd(II) and Zn(II) Metal Complexes

Authors

  • Hamsa Thamer Sadeq Department of Chemistry, College of Science, Al-Nahrain University, Baghdad-Iraq.

Keywords:

Schiff base, Pyridine, Zinc (ΙΙ), Cadmium (ΙΙ)

Abstract

A new nitrogen sulphur Schiff base has been prepared from the condensation 1-(pyridin-4-yl) ethanone with 3-methylbenzyl hydrazinecarbodithioate leading the formation of new ligand 3-methylbenzyl (2Z)-2-[1-(pyridin-4-yl)ethylidene]hydrazine carbodithioate (PE3MBC). The ligand was reacted with Cd(II) and Zn(II) metal salts to form new coordinated complexes. The new ligand and its metal complexes were characterized via various physico-chemical and spectroscopic techniques and conductivity, magnetic susceptibility of metal complexes based on the data analysis the metal complexes are expected to be tetrahedral in geometry.

Published

2013-09-01

Issue

Section

Articles

How to Cite

(1)
Preparation and Spectroscopic Study of New NS Ligand and Its Cd(II) and Zn(II) Metal Complexes. ANJS 2013, 16 (3), 72-78.